Fumaric Acid Commercial SDS MSDS of Manufacturers

Mubychem Limited of USA & India is a pioneer manufacturers suppliers exporters & importers of chemicals including Hydraulic fracturing stimulation & oil well production chemicals, Pharmaceutical excipients, Fragrance & flavor chemicals. Muby Chem Ltd has several manufacturing facilities and toll manufacturers across the globe. We have offices warehouses and representatives in Houston & Midland Texas and Chicago Illinois USA.

Our suppliers have accreditations like FDA - GMP-GLP approval, ISO-9001, ISO-22000 HACCP, Kosher & Halal Certification. We offer Commercial Pure Pharmacopoeia Analytical Reagent & Food Grade of Chemicals and do Toll Manufacturing for Oil well drilling fracking fracturing and others.

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GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910

Classification according to Regulation (EC) No 1272/2008
Serious eye damage/eye irritation Category 2A

Precautionary statements:
P264: Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.

Inhalation: If Fumaric Acid is inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources.

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of Fumaric Acid may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Avoid dust formation and control ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere. Emptying contents into a non-inert atmosphere where flammable vapors may be present could cause a flash fire or explosion due to electrostatic discharge.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

Appearance: Fumaric Acid is white to off-white crystals or powder.
Odor: Faint odor.
Solubility: Soluble in water.
Density: 1,63 g/cm3 at 20 °C
pH: Approximately 2, Acidic.
% Volatile by volume @ 21C (70F): 0
Molecular Weight: 116.07
Chemical Formula: HOOCCH=CHCOOH
Melting Point: 298 - 300°C - lit.

Stability: Fumaric Acid is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Excessive heat, Strong oxidizers.
Conditions to Avoid: Heat, dusting and incompatibles.

LD50 Oral - Rat - female: 9.300 mg/kg
LD50 Dermal - Rabbit - female: 20.000 mg/kg
LD50 Intraperitoneal - Mouse: 100 mg/kg
--------\Cancer Lists\-----------------------------------------
------------------------- NTP Carcinogen---
Ingredient -------------- Known -- Anticipated -- IARC Category
------------------------- -------- ----------- -------------
Fumaric Acid (110-16-7) --- No ----- No -------- -- None

Toxicity to fish daphnia and bacteria:
Toxicity to fish mortality: Danio rerio (zebra fish) - 245 mg/l - 48 h
Toxicity to fish semi-static test LC50: Danio rerio (zebra fish) - > 100 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates Immobilization EC50: Daphnia magna (Water flea) - 212 mg/l - 48 h
Toxicity to algae Growth inhibition EC50: Pseudokirchneriella subcapitata - > 100 mg/l - 72 h
Toxicity to bacteria Respiration inhibition EC50: activated sludge - > 300 mg/l - 3 h
Mobility in soil: No data available

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Fumaric Acid in accordance with legal requirements.

DOT: Not regulated
TDG: Not regulated
IATA: Not regulated
IMDG/IMO: Not regulated

USA Regulations:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
The reportable quantity (RQ) for this material is 5000 pounds. If appropriate, immediately report to the National Response Center (800/424-8802) as required by U.S.Federal Law. Also contact appropriate state and local regulatory agencies.
SARA Section 311/312 (40 CFR 370) Hazard Categories: Acute Health Hazard, Chronic Health Hazard.
SARA Section 313 (40 CFR 372) Hazard Categories: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
California Prop 65: This product contains no chemical known by the State of California to cause cancer, birth defects or other reproductive harm.

Disclaimer:
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Our company provides this MSDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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